Apparent Sintering Activation Energy Estimated by Master Sintering Curves for 8mol% Y<sub>2</sub>O<sub>3</sub> Doped ZrO<sub>2</sub> Polycrystals during Shrinkage-Rate Controlled Flash Sintering
نویسندگان
چکیده
The apparent activation energy of sintering for 8-mol%-Y2O3-doped ZrO2 during shrinkage-rate-controlled flash was determined using a master curve. SCF found to decrease from approximately 700 430 kJ/mol with density. in high-density region is similar value lattice diffusion, 460 kJ/mol. relative density range over which the occurred smaller than thermal and further moved lower temperature range. increase shrinkage rate at temperatures that occurs could be considered related this energy.
منابع مشابه
Master sintering curve for Gd-doped CeO2 solid electrolytes
The sintering behavior of gadolinia-doped ceria powders was studied by the master sintering curve (MSC). Dilatometric analyses of powders produced by a soft chemical method were performed to provide the experimental data set for the construction of the MSC. The assumed model provided good fittings of the MSC and the activation energy for the sintering of Ce1-xGdxO3-d, with x = 0, 0.05, 0.1, and...
متن کامل8YSZ sintering by flash sintering method and evaluation of process parameters
Flash sintering as a new sintering method for sintering of ceramic materials has been studied and effect of various parameter such as flash current density, time of flash and contact paste on properties of flash sintered 8YSZ samples has been investigated. Results showed it is possible to achieve high density in shorter time and lower temperature than conventional sintering methods. Samples cou...
متن کاملUltrafast-Contactless Flash Sintering using Plasma Electrodes
This paper presents a novel derivative of flash sintering, in which contactless flash sintering (CFS) is achieved using plasma electrodes. In this setup, electrical contact with the sample to be sintered is made by two arc plasma electrodes, one on either side, allowing current to pass through the sample. This opens up the possibility of continuous throughput flash sintering. Preheating, a usua...
متن کاملProbing the densification mechanisms during flash sintering of ZnO
Using ZnO as a model system, the densification mechanisms of flash sintering are investigated. Controlled experiments via limiting the maximum current or the effective ramp rate suggest that both the maximum specimen temperature and the high heating rate (on the order of 200 C/s) are essential for the rapid densification during the flash sintering. Moreover, benchmarking rapid thermal annealing...
متن کاملStudy on appropriate and modified conditions for flash sintering process by simulation modeling
Flash sintering is one of the newest techniques for sintering ceramics to near full density. It occurs in an appropriate combination of temperature and electric field. Temperature measurement is one of the most serious challenges in this process. In the present study, we tried to model a flash sintering process of 8YSZ and 3YSZ with finite element method to make an assessment for temperature di...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Materials transactions
سال: 2023
ISSN: ['1345-9678', '1347-5320']
DOI: https://doi.org/10.2320/matertrans.mt-m2023048